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Yo les paso estos Headers.
hServidor.Request.CustomHeaders.AddValue('Accept', '*/*');
hServidor.Request.CustomHeaders.AddValue('Accept-Encoding', 'identify');
hServidor.Request.CustomHeaders.AddValue('Charset', 'utf-8');
hServidor.Request.CustomHeaders.AddValue('Content-Type', 'text/xml');
hServidor.Request.CustomHeaders.AddValue('Connection', 'keep-alive');
hServidor.Request.CustomHeaders.AddValue('SOAPAction', 'checkVatService');
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